Asymmetric [2+2] photocycloaddition <i>via</i> charge transfer complex for the synthesis of tricyclic chiral ethers
نویسندگان
چکیده
The asymmetric synthesis of chiral polycyclic ethers by an intramolecular [2+2] photocycloaddition is described.
منابع مشابه
Asymmetric total synthesis of (+)-indatraline via diastereoselective amination of chiral ethers using chlorosulfonyl isocyanate
A concise asymmetric total synthesis of (þ)-indatraline from readily available cinnamic acid is described. The key steps include Corey’s oxazaborolidine-catalyzed asymmetric carbonyl reduction and a highly stereoselective amination of chiral benzylic ether with retention of stereochemistry using chlorosulfonyl isocyanate. 2013 Elsevier Ltd. All rights reserved.
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ژورنال
عنوان ژورنال: Chemical Communications
سال: 2021
ISSN: ['1359-7345', '1364-548X']
DOI: https://doi.org/10.1039/d1cc00035g